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Home/e-Resources/Materials Science/Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes
PeriodicalsMaterials Science

Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes

Qianqian Hu·Jie Chen·Yang Yang·Hui Yang·Ling Ping Zhou
Tetrahedron Chem2024

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Abstract & Overview

Bicyclo[1.1.0]butanes (BCBs) and [1.1.1]propellanes (tricyclo[1.1.1.01,3]pentanes, TCPs) are structurally unique compounds with different chemical properties. Strain-release driven reactions have emerged as an atom- and step-economic strategy for the organic synthesis. Using this strategy, a variety of functional ring molecules have been efficiently synthesized, including various cyclobutane molecules, bicyclo[2.1.1]hexanes, bicyclo[1.1.1]pentanes, and others. More specifically, these strain release-driven reactions include aspects of nucleophilic addition, radical addition, electrophilic or transition metal catalysis. This review will discuss the recent developments in the strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes.

Cite this record

Qianqian Hu, Jie Chen, Yang Yang, Hui Yang, Ling Ping Zhou (2024). Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes. Tetrahedron Chem, 9, 100070–100070. https://doi.org/10.1016/j.tchem.2024.100070

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Hu, Q., Chen, J., Yang, Y., Yang, H., & Zhou, L. P. (2024). Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes. Tetrahedron Chem, 9, 100070–100070. https://doi.org/10.1016/j.tchem.2024.100070
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