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Home/e-Resources/Chemistry/Redetermination of the high-pressure modification of AlOOH from single-crystal synchrotron data
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Redetermination of the high-pressure modification of AlOOH from single-crystal synchrotron data

Kazuki Komatsu·Takahiro Kuribayashi·Asami Sano‐Furukawa·Eiji Ohtani·Yasuhiro Kudoh
Acta Crystallographica Section E Structure Reports Online2006

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Abstract & Overview

The single-crystal synchrotron study of the high-pressure modification of aluminium oxide hydroxide, δ-AlOOH, confirms the previous structure determination in the space group P21nm, which was based on X-ray powder data [Suzuki, Ohtani & Kamada (2000). Phys. Chem. Miner. 27, 689–693]. The present study includes the determination of the H-atom parameters, which revealed a strong asymmetric hydrogen bond with an O⋯O distance of 2.5479 (12) Å. The δ-AlOOH structure is isotypic with that of β-CrOOH and may be considered as a distorted rutile type with all atoms located on mirror planes.

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Kazuki Komatsu, Takahiro Kuribayashi, Asami Sano‐Furukawa, Eiji Ohtani, Yasuhiro Kudoh (2006). Redetermination of the high-pressure modification of AlOOH from single-crystal synchrotron data. Acta Crystallographica Section E Structure Reports Online, 62(11), i216–i218. https://doi.org/10.1107/s160053680603916x

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Komatsu, K., Kuribayashi, T., Sano‐Furukawa, A., Ohtani, E., & Kudoh, Y. (2006). Redetermination of the high-pressure modification of AlOOH from single-crystal synchrotron data. Acta Crystallographica Section E Structure Reports Online, 62(11), i216–i218. https://doi.org/10.1107/s160053680603916x
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